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AbstractSodium ion secondary variety (SIB) Is a low cost and allpervasive secondary battery for next generation large scale energy storage. The diffusion process of large Na+ (Ionic distance is 1.12 ), unfortunately, Is widely known as slower than that of small Li+ (0.76 ). This would be a serious disadvantage of SIB as compared with the Lithium ion secondary battery (LIB). with the electrochemical impedance spectroscopy (EIS), We decided on the diffusion constant (defense) Of Na+ in thin films of O3 and P2 type NaCoO2 with layered homes. We found that a D values ( 0.5 1.5 1010cm2/s) Of Na+ are as compared to those (11cm2/s) Of Li+ in layered LiCoO2. rather, The D values of O3 NaCoO2 are even greater than those of P2 NaCoO2, Probably because O3 NaCoO2 shows successive structural phase changes from the O3, O’3, P’3, To P3 distinct levels with Na+ deintercalation. We further found that the initial energy (ed 0.4eV) For the Na+ diffusion is radically low in these layered cobalt oxides. conversely, The Na+ diffusion is really obsessed with the crystal structure. as an example, those Na+ diffusion in P2 Na0.66Li0.22Ti0.78O2 with layered structure12 and Na3V2(PO4)313 with the help of NASICON (Na extra Ionic CONductor) Structure are sufficiently fast, while it is much slower in Li4Ti5O1214,15 with spinel rule. to help precisely determine the Na+ diffusion constant (deb), We fabricated thin films of O3 and P2 type NaCoO2 on an Au collector electrode by using the pulsed laser deposition (PLD) techniques. We found that your D values ( 0.5 1.5 1010cm2/s) Of Na+ are beyond those (1 1011cm2/s16) Of Li+ in split LiCoO2.

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